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Ingersoll, George P

Seasonal snowpack chemistry data from the Rocky Mountain region of the US was examined to identify long-term trends in concentration and chemical deposition in snow and in snow-water equivalent. For the period 1993?2004, comparisons of trends were made between 54 Rocky Mountain Snowpack sites and 16 National Atmospheric Deposition Program wetfall sites located nearby in the region. The region was divided into three subregions: Northern, Central, and Southern. A non-parametric correlation method known as the Regional Kendall Test was used. This technique collectively computed the slope, direction, and probability of trend for several sites at once in each of the Northern, Central, and Southern Rockies subregions....
Volume-weighted mean concentrations of nitrate (NO3?), ammonium (NH4+), and sulfate (SO42?) in precipitation were compared at high-elevation sites in Colorado from 1992 to 1997 to evaluate emission source areas to the east and west of the Rocky Mountains. Precipitation chemistry was measured by two sampling methods, the National Atmospheric Deposition Program/National Trends Network (NADP/NTN) and snowpack surveys at maximum accumulation. Concentrations of NO3? and SO42? in winter precipitation were greater on the western slope of the Rockies, and concentrations of NO3? and NH4+ in summer precipitation were greater on the eastern slope. Summer concentrations in general were almost twice as high as winter concentrations....
Seasonal snowpack chemistry data from the Rocky Mountain region of the US was examined to identify long-term trends in concentration and chemical deposition in snow and in snow-water equivalent. For the period 1993?2004, comparisons of trends were made between 54 Rocky Mountain Snowpack sites and 16 National Atmospheric Deposition Program wetfall sites located nearby in the region. The region was divided into three subregions: Northern, Central, and Southern. A non-parametric correlation method known as the Regional Kendall Test was used. This technique collectively computed the slope, direction, and probability of trend for several sites at once in each of the Northern, Central, and Southern Rockies subregions....
Trends in snow acidity reflect the balance between strong acid inputs and reactions with neutralizing materials. Carbonate dust can be an important contributor of buffering capacity to snow; however, its concentration in snow is difficult to quantify because it dissolves rapidly in snowmelt. In snow with neutral or acidic pH, most calcite would dissolve during sample melting if snow samples were processed using standard techniques. Here a method is described for separating particulate carbonate matter from snow. Snow samples were melted in solutions close to saturation with calcite, decreasing the dissolution rate by a factor of 100?200 compared with natural melting of snow. Particulate matter larger than 0.45 ?m...
Depth-integrated snowpack chemistry was measured just prior to maximum snowpack depth during the winters of 1992?1999 at 12 sites co-located with National Atmospheric Deposition Program/National Trend Network (NADP/NTN) sites in the central and southern Rocky Mountains, USA. Winter volume-weighted mean wet-deposition concentrations were calculated for the NADP/NTN sites, and the data were compared to snowpack concentrations using the paired t-test and the Wilcoxon signed-rank test. No statistically significant differences were indicated in concentrations of SO42? or NO3? (p>0.1). Small, but statistically significant differences (p0.03) were indicated for all other solutes analyzed. Differences were largest for Ca2+...
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