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Natural cave passages penetrating a coastal aquifer in the Yucatan Peninsula (Mexico) were accessed to test the hypothesis that chemoclines associated with salinity gradients (haloclines) within the flooded cave networks of the karst subterranean estuary are sites of methane oxidation. Two field trips were carried out to the fully-submerged cave system located 6.6 km inland from the coastline in January 2015 and January 2016. Vertical chemical profiles across the water column haloclines were obtained using the OctoPiPi (OPP), a high-resolution water sampler built by the U.S. Geological Survey (USGS). The sampling efforts resulted in cm-scale profiles of major ions (e.g., chloride and sulfate), as well as concentrations...
Subterranean estuaries extend inland into density-stratified coastal carbonate aquifers that contain a surprising diversity of endemic animals (mostly crustaceans) within a highly oligotrophic environment. How complex ecosystems thrive in this globally-distributed, cryptic habitat (termed anchialine) is poorly understood. The northeastern margin of the Yucatan Peninsula contains over 250 km of mapped, diver-accessible caves passages where previous studies have suggested chemoautotrophic processes are the source of carbon and energy sustaining the anchialine food web. This dataset, collected during four field events during U.S. Geological Survey (USGS) Coastal and Marine Geology Program Field Activities 2015-013-FA...
Categories: Data;
Types: Citation;
Tags: Cenote Bang,
Mexico,
Ox Bel Ha Cave System,
Quintana Roo, Mexico,
Yucatan Peninsula,
Assessment of geochemical cycling within tidal wetlands and measurement of fluxes of dissolved and particulate constituents between wetlands and coastal water bodies are critical to evaluating ecosystem function, service, and status. The U.S. Geological Survey and collaborators collected surface water and porewater geochemical data from a tidal wetland located on the eastern shore of Sage Lot Pond in Mashpee, Massachusetts, within the Waquoit Bay National Estuarine Research Reserve, between 2012 and 2019. Additional porewater geochemical and field data from a tidal wetland on the eastern shore of Great Pond in East Falmouth, MA are also included. These data can be used to evaluate biogeochemical conditions and cycling...
Categories: Data,
Data Release - Revised;
Tags: Climatology,
Environmental Health,
USGS Science Data Catalog (SDC)
A critical question for assessing global greenhouse gas budgets is how much of the methane that escapes from seafloor cold seep sites to the overlying water column eventually crosses the sea-air interface and reaches the atmosphere. The issue is particularly important in Arctic Ocean waters since rapid warming there increases the likelihood that gas hydrate--an ice-like form of methane and water stable at particular pressure and temperature conditions within marine sediments--will break down and release its methane to the overlying ocean. Some researchers have even proposed the possibility of an Arctic methane catastrophe characterized by wholesale breakdown of gas hydrates in marine sediments and release of the...
A discrete sample introduction module (DSIM) was developed and interfaced to a cavity ring-down spectrometer to enable measurements of methane and CO2 concentrations and 13C values with a commercially available cavity ring-down spectrometer (CRDS). The DSIM-CRDS system permits the analysis of limited volume (5 - 100-ml) samples ranging six orders-of-magnitude from 100% analyte to the lower limit of instrument detection (2 ppm). We demonstrate system performance for methane by comparing concentrations and 13C results obtained by the DSIM and traditional methods for a variety of sample types, including low concentration (nanomolar) seawater and high concentration (> 90%) natural gas. The expansive concentration range...
Categories: Data;
Tags: Geochemistry,
Temperate Northern Atlantic,
Temperate Northern Pacific,
U.S. Geological Survey,
USGS,
Natural cave passages penetrating coastal aquifers in the Yucatan Peninsula (Quintana Roo, Mexico) were accessed to investigate how regional meteorology and hydrology control dissolved organic carbon and methane dynamics in karst subterranean estuaries, the region of aquifers where fresh and saline waters mix. Three field trips were carried out in December 2013, August 2014, and January 2015 to obtain 1) physicochemical and 2) geochemical data from the water column and 3) temporal records of water chemistry and hydrological parameters below and above the surface at three sites within the Ox Bel Ha cave (Cenote Jailhouse, Cenote Naach Wennen Ha, and Cenote Odyssey) and another cave (Cenote Crustacea). These efforts...
Subterranean estuaries extend inland into density-stratified coastal carbonate aquifers that contain a surprising diversity of endemic animals (mostly crustaceans) within a highly oligotrophic environment. How complex ecosystems thrive in this globally-distributed, cryptic habitat (termed anchialine) is poorly understood. The northeastern margin of the Yucatan Peninsula contains over 250 km of mapped, diver-accessible caves passages where previous studies have suggested chemoautotrophic processes are the source of carbon and energy sustaining the anchialine food web. This dataset, collected during four field events during U.S. Geological Survey (USGS) Coastal and Marine Geology Program Field Activities 2015-013-FA...
Natural cave passages penetrating a coastal aquifer in the Yucatan Peninsula (Mexico) were accessed to investigate how regional meteorology and hydrology control methane dynamics in karst subterranean estuaries. Three field trips were carried out in January 2015, June 2015, and January 2016 to obtain year-long high-resolution temporal records of water chemistry and environmental parameters below and above the surface at a site (Cenote Bang) within the Ox Bel Ha cave network. These efforts resulted in chemical records of dissolved methane concentrations and its stable carbon isotopic content and major ion concentrations (i.e., chloride and sulfate) in approximately 2.5-day resolution from January 2015 to January...
Natural cave passages penetrating coastal aquifers in the Yucatan Peninsula (Quintana Roo, Mexico) were accessed to investigate how regional meteorology and hydrology control dissolved organic carbon and methane dynamics in karst subterranean estuaries, the region of aquifers where fresh and saline waters mix. Three field trips were carried out in December 2013, August 2014, and January 2015 to obtain 1) physicochemical and 2) geochemical data from the water column and 3) temporal records of water chemistry and hydrological parameters below and above the surface at three sites within the Ox Bel Ha cave (Cenote Jailhouse, Cenote Naach Wennen Ha, and Cenote Odyssey) and another cave (Cenote Crustacea). These efforts...
Categories: Data;
Tags: Cenote Crustacea,
Cenote Jailhouse,
Cenote Naach Wennen Ha,
Cenote Odyssey,
Mexico,
Natural cave passages penetrating coastal aquifers in the Yucatan Peninsula (Quintana Roo, Mexico) were accessed to investigate how regional meteorology and hydrology control dissolved organic carbon and methane dynamics in karst subterranean estuaries, the region of aquifers where fresh and saline waters mix. Three field trips were carried out in December 2013, August 2014, and January 2015 to obtain 1) physicochemical and 2) geochemical data from the water column and 3) temporal records of water chemistry and hydrological parameters below and above the surface at three sites within the Ox Bel Ha cave (Cenote Jailhouse, Cenote Naach Wennen Ha, and Cenote Odyssey) and another cave (Cenote Crustacea). These efforts...
Categories: Data;
Tags: Cenote Crustacea,
Cenote Jailhouse,
Cenote Naach Wennen Ha,
Cenote Odyssey,
Mexico,
Natural cave passages penetrating coastal aquifers in the Yucatan Peninsula (Quintana Roo, Mexico) were accessed to investigate how regional meteorology and hydrology control dissolved organic carbon and methane dynamics in karst subterranean estuaries, the region of aquifers where fresh and saline waters mix. Three field trips were carried out in December 2013, August 2014, and January 2015 to obtain 1) physicochemical and 2) geochemical data from the water column and 3) temporal records of water chemistry and hydrological parameters below and above the surface at three sites within the Ox Bel Ha cave (Cenote Jailhouse, Cenote Naach Wennen Ha, and Cenote Odyssey) and another cave (Cenote Crustacea). These efforts...
Categories: Data;
Tags: Cenote Naach Wennen Ha,
Cenote Odyssey,
Mexico,
Ox Bel Ha Cave System,
Quintana Roo,
Subterranean estuaries extend inland into density-stratified coastal carbonate aquifers that contain a surprising diversity of endemic animals (mostly crustaceans) within a highly oligotrophic environment. How complex ecosystems thrive in this globally-distributed, cryptic habitat (termed anchialine) is poorly understood. The northeastern margin of the Yucatan Peninsula contains over 250 km of mapped, diver-accessible caves passages where previous studies have suggested chemoautotrophic processes are the source of carbon and energy sustaining the anchialine food web. This dataset, collected during four field events during U.S. Geological Survey (USGS) Coastal and Marine Geology Program Field Activities 2015-013-FA...
Categories: Data;
Types: Citation;
Tags: Cenote Bang,
Mexico,
Ox Bel Ha Cave System,
Quintana Roo, Mexico,
Yucatan Peninsula,
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