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One phenomenon that has been shown to concentrate and release per- and polyfluoroalkyl substances (PFAS) in surface water is the formation of natural foams. For surface water foams to form, surface active compounds or surfactants must be present in the water along with a source of gas bubbles. Some examples of surface-active compounds include humic and fulvic acids, colloidal particles, and lipids and proteins. The relationship between PFAS and dissolved organic matter (DOM) is important because studies have shown that DOM can affect PFAS fate and bioavailability in aquatic systems and treatment processes. The results from this assessment will improve our understanding of PFAS fate and transport in the environment....
Categories: Data;
Tags: California,
California Water Science Center,
DOM,
Geochemistry,
Organic Matter Research Lab,
The dataset documents the spatial and temporal variability of nutrients, phytoplankton, and related water quality parameters at high spatial resolution in the Sacramento-San Joaquin River Delta and Suisun Bay of California, USA. The dataset includes nitrate, ammonium, orthophosphate, dissolved organic carbon, temperature, conductivity, dissolved oxygen, and chlorophyll as well as information about phytoplankton community composition. Data were collected under different environmental/flow conditions in June, July, August, and October of 2020, and May, July, and October of 2021. The data release consists of a .xml document, and .txt and shapefile documents. Descriptions for each document and file are listed in the...
This data release documents the spatial and temporal variability of nutrients and related water quality parameters at high spatial resolution in Suisun Marsh and Suisun Bay in the San Francisco Estuary of California, USA. The data set includes nitrate, ammonium, phosphate, dissolved organic carbon, temperature, conductivity, dissolved oxygen, turbidity, chlorophyll, blue-green algal pigments, and phytoplankton community structure. Data-collection cruises were conducted under three different environmental/flow conditions between July - September 2018 that coincided with conditions prior to, during, and following the Suisun Marsh Salinity Control Gates Summer Action. The action is part of the Delta Smelt Resiliency...
Categories: Data;
Tags: California,
Central Valley,
Geochemistry,
Sacramento River,
Sacramento-San Joaquin Delta,
Here we report optical data collected as part of a collaborative study between USGS Pennsylvania Water Science Center, Pennsylvania Department of Environmental Protection and Water Mission Area Proxies Project. The optical measurements reported here were collected to aide in the characterization of water sources and mixtures and establish proxies (surrogates) for per- and poly-fluorinated alkyl substances within the Neshaminy Creek basin. Data are compiled into three tables: 1) full fluorescence spectra in vectorized format, 2) full absorbance spectra, and 3) summary file of commonly extracted optical indicators and field-based sensor arrays.
Categories: Data;
Tags: California,
California Water Science Center,
Environmental Health,
Geochemistry,
Organic Matter Research Lab,
The use of field-deployable fluorescence sensors to better understand dissolved organic matter concentrations and composition has grown immensely in recent years. Applications of these sensors to critical monitoring efforts have also grown to encompass post-fire monitoring, wastewater tracking, and use as a proxy for various contaminants. Despite the growth, it is well known that these sensors are subject to various interferences and require corrections for temperature, turbidity, and concentration effects. Although temperature corrections are widely applicable across sensors, the turbidity and concentration corrections can be site-specific and/or sensor-specific. The corrections can even be subject to changes in...
Categories: Data;
Tags: DOC,
USGS California Water Science Center,
USGS Science Data Catalog (SDC),
Water Quality,
biota,
The USGS CAWSC Organic Matter Research Laboratory (OMRL) provides laboratory services and support to regional and national projects in the analysis of organic matter using the latest methods in absorbance and fluorescence spectroscopy. Optical measurements such as absorbance and fluorescence are used to gain insight into dissolved organic matter (DOM) composition, and can also serve as proxies for more expensive and difficult to obtain measurements. These techniques are relatively rapid and inexpensive and allow for the comprehensive tracking of DOM dynamics in aquatic ecosystems ranging from rivers and lakes to estuaries to open marine systems. Absorbance spectra and fluorescence matrices were simultaneously collected...
Categories: Data;
Tags: Aqualog,
California,
California Water Science Center,
Dissolved Organic Matter,
Fluorescence,
The dataset documents the spatial and temporal variability of nutrients and related water quality parameters at high spatial resolution in the North Delta of the Sacramento-San Joaquin River Delta of California, USA. The dataset includes surface mapping, depth profile, and discrete data for nitrate, ammonium, phosphate, dissolved organic carbon, temperature, conductivity, dissolved oxygen, and chlorophyll as well as information about phytoplankton community composition. Data-collection cruises were conducted over two time periods in July and October 2018 across two flooded islands with dense submerged aquatic vegetation beds. Little Hastings Tract received an herbicide treatment by the California Department of Boating...
Optical sensors measuring fluorescence of non-biological sources (e.g., dissolved organic matter, wastewater, hydrocarbons, fluorescent dyes, etc.; hereafter referred to as fDOM) are increasingly used in water quality studies because they provide proxy measurements for a variety of contaminants and constituents of concern including metals, wastewater effluent, and DOM (measured in the lab as dissolved organic carbon, (DOC)) concentrations. Similarly, sensors measuring biological (algal) fluorescence (hereafter referred to as chlorophyll (fChl) and phycocyanin (fPC), have gained popularity to measure phytoplankton concentration, biomass, and even primary productivity. As additional sensors are coupled with ongoing...
Categories: Data,
Data Release - Revised;
Tags: California,
California Water Science Center,
EXO YSI,
Organic Matter Research Laboratory,
Sacramento,
The USGS CAWSC Organic Matter Research Laboratory (OMRL) provides laboratory services and support to regional and national projects in the analysis of organic matter using the latest methods in absorbance and fluorescence spectroscopy. Optical measurements such as absorbance and fluorescence are used to gain insight into dissolved organic matter (DOM) composition, and can also serve as proxies for more expensive and difficult to obtain measurements. These techniques are relatively rapid and inexpensive and allow for the comprehensive tracking of DOM dynamics in aquatic ecosystems ranging from rivers and lakes to estuaries to open marine systems. Absorbance spectra and fluorescence matrices were simultaneously collected...
Categories: Data;
Tags: Absorbance,
Aqualog,
California,
California Water Science Center,
Dissolved Organic Matter,
Note: this data release has been superseded by version 2.0, available here: https://doi.org/10.5066/P91LJNAU Optical sensors measuring fluorescent dissolved organic matter (fDOM) are increasingly being used in water quality studies because they provide proxy measurements for dissolved organic matter concentrations (DOC). Similarly, chlorophyll-a (chl-a) fluorescence sensors have gained popularity as a means to measure phytoplankton concentration, biomass, and even primary productivity using various approaches. As additional sensors are grouped for in situ monitoring, field calibration checks are becoming quite time consuming for even the basic set of sensors (i.e. pH, specific conductivity, turbidity) that require...
Categories: Data;
Tags: California,
California Water Science Center,
EXO YSI,
Organic Matter Research Laboratory,
Sacramento,
The dataset documents the spatial and temporal variability of nutrients and related water quality parameters at high spatial resolution in the North Delta, Central Delta, and the Western Delta out to Suisun Bay in the Sacramento-San Joaquin River Delta of California, USA. The dataset includes nitrate, ammonium, phosphate, dissolved organic carbon, temperature, conductivity, dissolved oxygen, and chlorophyll as well as information about phytoplankton community composition. Data-collection cruises were conducted under three different environmental/flow conditions in May, July, and October of 2018. The data release consists of a xml document, 13 text/csv documents, and a zip file. Descriptions for each document and...
Categories: Data;
Tags: California,
Central Valley,
Liberty Island,
Sacramento River,
Sacramento-San Joaquin Delta,
Data was collected in the Cache Slough Complex located in the northern San Francisco Estuary to characterize water quality parameters at high spatial resolution. Data collection was conducted on three separate occasions: October 2017, May 2018, and October 2018. Data set includes nitrate, ammonium, ortho-phosphate, dissolved organic carbon, temperature, conductivity, dissolved oxygen, turbidity, chlorophyll, stable isotopes including water isotopes. Measurements were used to calculate evaporation to inflow ratios and water residence time.
Here, we present the results supporting Table 2 in Field Techniques for Fluorescence Measurements Targeting Dissolved Organic Matter, Hydrocarbons, and Wastewater in Environmental Waters: Principles and Guidelines for Instrument Selection, Operation and Maintenance, Quality Assurance, and Data Reporting. Table 2 shows comparisons from an Aqualog 800 benchtop fluorometer standardized to quinine sulfate equivalents (QSE) with excitation (ex) and emissions (em) equivalent to fluorescence of dissolved organic matter (fDOM) sensors from multiple manufacturers. Data are reported from two standard reference materials (SRM) and the mean, minimum, and maximum from 76 environmental samples. No replicates were collected for...
Categories: Data;
Tags: California,
California Water Science Center,
DOC,
Organic Matter Research Laboratory,
Sacramento,
This data release documents the spatial and temporal variability of nutrients and related water quality parameters at high spatial resolution in the western and central portion of the Sacramento-San Joaquin River Delta of California, USA. The data set includes water residence time, nitrate, ammonium, phosphate, dissolved organic carbon, temperature, conductivity, dissolved oxygen, turbidity, and chlorophyll. Data collection were conducted over six days between August 2015 - July 2016 to document conditions prior to, during, and following the installation of a rock barrier on False Barrier to limit salt intrusion.
Categories: Data;
Tags: California,
Central Valley,
Geochemistry,
Sacramento River,
Sacramento-San Joaquin Delta,
Here, we present data supporting temporal variability and sources of PFAS in the Rio Grande through an arid urban area using high-frequency sampling and novel samplers. Data are compiled into two tables: 1) full fluorescence spectra in vectorized format, and 2) summary file of concentrations of total dissolved nitrogen and commonly extracted field-based sensor arrays. Data are reported from two sites at Rio Grande, New Mexico during a 24-hour collection period. Two field blanks, one field replicate, and two laboratory replicates are reported for 26 environmental samples.
Categories: Data;
Tags: California,
Organic Matter Research Lab,
Sacramento,
TDN,
USGS Science Data Catalog (SDC),
Optical sensors measuring fluorescence of dissolved organic matter (fDOM) are increasingly used in water quality studies because they provide proxy measurements for a variety of contaminants and constituents of concern including metals and wastewater effluent. Similarly, sensors measuring fluorescence of chlorophyll (fChl) and phycocyanin (fPC) have gained popularity to measure phytoplankton concentration, biomass, and even primary productivity. Optical sensors require calibration using a calibration standard solution which is diluted from a working stock solution. However, preparation of stock solutions is challenging because they are difficult to prepare accurately, need to be prepared in a laboratory setting,...
Categories: Data;
Tags: California,
California Water Science Center,
Organic Matter Research Lab,
Sacramento,
USGS Science Data Catalog (SDC),
The study is comprised of daily survey data consisting of high resolution mapping and discrete sample collection of nutrients, phytoplankton, and related water quality constituents conducted in the Sacramento River, Georgiana Slough, and the North and South Forks of the Mokelumne River on August 28 and September 10-12, 2019, coincident with planned holds of treated wastewater effluent from Sacramento Regional Wastewater Treatment Plant (SRWTP) on August 27 and September 9-11, 2019.
Categories: Data;
Tags: Aquatic Biology,
California,
Central Valley,
Georgiana Slough,
Lower Sacramento,
This dataset includes field measurements and laboratory analyses of surface water, bottom water (sediment-water interface), surficial (0-2 cm) sediment, pore water (0-2 cm), and biota collected in Lake Combie, California, from September 2017 through August 2021. The study area includes six sites within the reservoir where discrete samples of surface water, bottom water, sediment, and pore water were taken along the length of the reservoir at the following distances from the spillway: 0.07 miles, 0.5 miles, 0.9 miles, 1.2 miles, 1.3 miles, and 1.4 miles. The within-reservoir sites were sampled during September 2017, February 2018, and May 2018, prior to a large sediment removal operation, and again during September...
Fluorescence and absorbance spectra were measured in discrete surface water samples collected during three sampling campaigns (Nov 2022, Mar/Apr 2023, Jul 2023) on the Illinois Waterway (IWW) and Chicago Area Waterway System (CAWS), which are the primary drainage of the Illinois River Basin (IRB). Water sampling was conducted concurrently with a boat-based water quality mapping effort using the Fast Limnology Automated Measurement (FLAMe) system (Crawford et al., 2015). Each campaign began in the Chicago metropolitan area, and after having sampled Lake Michigan, entered into the upper extent of the IWW, sampling through the CAWS into the lower reaches of the Des Plaines River and finally the Illinois River. After...
Categories: Data;
Tags: Absorbance,
Aqualog,
California,
California Water Science Center,
Dissolved Organic Matter,
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