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The transport of dissolved organic matter (DOM) by rivers is an important component of the global carbon cycle, affects ecosystems and water quality, and reflects biogeochemical and hydrological processes in watersheds. Understanding the fundamental relationships between discharge and DOM concentration and composition reveals important information about watershed flow paths, soil flushing, connectivity to riparian zones, organic matter leaching, soil moisture, and climatic influences. Data to describe these processes - both magnitude and timing - is critical for modeling and predicting watershed DOM dynamics, particularly in light of land use and climate change . Despite several decades of data collection, a synthesis...
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Land Resources,
River,
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Recent studies have found insignificant or decreasing trends in time-series dissolved organic carbon (DOC) datasets, questioning the assumption that long-term DOC concentrations in surface waters are increasing in response to anthropogenic forcing, including climate change, land use, and atmospheric acid deposition. We used the Weighted Regressions on Time, Discharge, and Season (WRTDS) model to estimate annual flow-normalized (FN) concentrations and fluxes to determine if changes in DOC quantity and quality signal anthropogenic forcing at 10 locations in the Mississippi River Basin (MRB). Despite increases in agriculture and urban development throughout the basin, net increases in DOC concentration and flux were...
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A better understanding of how hydrological and biogeochemical processes control dissolved organic carbon (DOC) concentrations and dissolved organic matter (DOM) composition from headwaters downstream to large rivers is needed. We examined a large DOM dataset from the National Water Information System of the U.S. Geological Survey, which represents approximately 100,000 measurements of DOC concentration and DOM composition at many sites along rivers across the United States. Application of quantile regression revealed a tendency towards downstream spatial and temporal homogenization of DOC concentrations and a shift from dominance of aromatic DOM in headwaters to more aliphatic DOM downstream. The DOC concentration...
Categories: Publication;
Types: Citation
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