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EXTRACTOR is a program that extracts data from formatted and labeled MODFLOW head or drawdown files or from MODFLOW-GWT concentration or velocity files. The user specifies the number of rows, columns, and layers in the target data file, the desired time step or move number, and the range of rows, columns, and layers for which data should be extracted and written to a new text file. The new text file can then be imported into other data-analysis programs.
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The inhibition of acetoclastic methanogenesis in crude oil- and creosote-contaminated groundwater was studied. The crude oil and water-soluble components of creosote contributed to the inhibition of acetoclastic methanogens. Acetoclastic methanogenesis was much more susceptible to the toxic inhibition of crude oil and creosote than either hydrogen- or formate-utilizing methanogenesis. The effect of this toxic inhibition was apparent in the population of the methanogenic trophic groups near nonaqueous crude oil at the Bemidji, MN, site. At a crude oil-contaminated site, numbers of acetoclastic methanogens found close to crude oil were 100 times fewer than those of hydrogen- and formate-utilizing methanogens. In laboratory...
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The Chesapeake Bay is the Nation‘s largest estuary and historically supported one of the most productive fisheries in the world. In addition to supporting aquatic communities and wildlife, the bay‘s watershed serves the economic and recreational needs of 15 million people. The fertile soils of the watershed support significant agricultural production. Unfortunately, the commercial, economic, and recreational value of the bay and its watershed has been degraded by poor water quality, loss of habitat, and overharvesting of living resources. Since the early 1980‘s, the Chesapeake Bay Program, which is a partnership among Maryland, Virginia, Pennsylvania, the District of Columbia, the Federal Government, and the Chesapeake...
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We report chemical and isotopic analyses of 345 water samples collected from the Osage-Skiatook Petroleum Environmental Research (OSPER) project. Water samples were collected as part of an ongoing multi-year USGS investigation to study the transport, fate, natural attenuation, and ecosystem impacts of inorganic salts and organic compounds present in produced water releases at two oil and gas production sites from an aging petroleum field located in Osage County, in northeast Oklahoma. The water samples were collected primarily from monitoring wells and surface waters at the two research sites, OSPER A (legacy site) and OSPER B (active site), during the period March, 2001 to February, 2005. The data include produced...
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The Chesapeake Bay, the Nation‘s largest estuary, has been degraded because of diminished water quality, loss of habitat, and over-harvesting of living resources. Consequently, the bay was listed as an impaired water body due to excess nutrients and sediment. The Chesapeake Bay Program (CBP), a multi-jurisdictional partnership, completed an agreement called ?Chesapeake 2000? that revises and establishes new restoration goals through 2010 in the bay and its watershed. The goal of this commitment is the removal of the bay from the list of impaired waterbodies by the year 2010. The CBP is committed to developing sediment and nutrient allocations for major basins within the bay watershed and to the process of examining...
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The chemical reactions that lead to the formation of dissolved organic matter (DOM) in natural waters are poorly understood. Studies on the formation of DOM generally are complicated because almost all DOM isolates have been derived from mixtures of plant species composed of a wide variety of different types of precursor compounds for DOM formation. This report describes a study of DOM derived mainly from bales of wheat straw that had been left in a field for several years. During this period of time, black water from the decomposing wheat straw accumulated in pools in the field. The nuclear magnetic resonance and infrared spectra of the black water DOM indicate that it is composed almost entirely of lignin and...
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GoPhast is a graphical user interface (GUI) for the USGS model PHAST. PHAST simulates multicomponent, reactive solute transport in three-dimensional, saturated, ground-water flow systems. PHAST can model both equilibrium and kinetic geochemical reactions. PHAST is derived from HST3D (flow and transport) and PHREEQC (geochemical calculations). The flow and transport calculations are restricted to constant fluid density and constant temperature. The complexity of the input required by PHAST makes manual construction of its input files tedious and error-prone. GoPhast streamlines the creation of the input file and helps reduce errors. GoPhast allows the user to define the spatial input for the PHAST flow and transport...
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This report describes modifications to a U.S. Geological Survey (USGS) three-dimensional solute-transport model (MODFLOW-GWT), which is incorporated into the USGS MODFLOW ground-water model as the Ground-Water Transport (GWT) Process. The modifications were made to create compatibility between the Multi-Node Well (MNW) Package for MODFLOW and the MODFLOW-GWT model. This compatibility improves the capability of MODFLOW-GWT to represent accurately solute transport in simulations that include multi-node wells because long-screen wells or long open boreholes that extend through multiple model layers can provide fast pathways for solutes to move from one location to another in a ground-water flow system. For nonpumping...
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This report describes modifications to a U.S. Geological Survey (USGS) threedimensional solute-transport model (MODFLOWGWT), which is incorporated into the USGS MODFLOW ground-water model as the Ground- Water Transport (GWT) Process. The modifications improve the capability of MODFLOW-GWT to accurately simulate solute transport in simulations that represent a nonzero flux across an aquifer boundary. In such situations, the new Boundary Flux Package (BFLX) will allow the user flexibility to assign the flux to specific cell faces, although that flexibility is limited for certain types of fluxes (such as recharge and evapotranspiration, which can only be assigned to the top face if either is to be represented as a...
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Analyses of stable isotope profiles (d2H and d18O) in the saturated zone, combined with water-table fluctuations, gave a comprehensive picture of recharge processes in an alluvial aquifer riparian zone. At the Norman Landfill U.S. Geological Survey Toxic Substances Hydrology research site in Norman, Oklahoma, recharge to the aquifer appears to drive biodegradation, contributing fresh supplies of electron acceptors for the attenuation of leachate compounds from the landfill. Quantifying recharge is a first step in studying this process in detail. Both chemical and physical methods were used to estimate recharge. Chemical methods included measuring the increase in recharge water in the saturated zone, as defined by...
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The increasing concern for water and its quality require improved methods to evaluate the interaction between streams and aquifers and the strong influence that streams can have on the flow and transport of contaminants through many aquifers. For this reason, a new Streamflow-Routing (SFR1) Package was written for use with the U.S. Geological Survey‘s MODFLOW-2000 ground-water flow model. The SFR1 Package is linked to the Lake (LAK3) Package, and both have been integrated with the Ground-Water Transport (GWT) Process of MODFLOW-2000 (MODFLOW-GWT). SFR1 replaces the previous Stream (STR1) Package, with the most important difference being that stream depth is computed at the midpoint of each reach instead of at the...
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This report describes SutraGUI, a flexible graphical user-interface (GUI) that supports two-dimensional (2D) and three-dimensional (3D) simulation with the U.S. Geological Survey (USGS) SUTRA ground-water-flow and transport model (Voss and Provost, 2002). SutraGUI allows the user to create SUTRA ground-water models graphically. SutraGUI provides all of the graphical functionality required for setting up and running SUTRA simulations that range from basic to sophisticated, but it is also possible for advanced users to apply programmable features within Argus ONE to meet the unique demands of particular ground-water modeling projects. SutraGUI is a public-domain computer program designed to run with the proprietary...
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Geochemical reaction path modeling is useful for rapidly assessing the extent of water-aqueous-gas interactions both in natural systems and in industrial processes. Modeling of some systems, such as those at low temperature with relatively high hydrologic flow rates, or those perturbed by the subsurface injection of industrial waste such as CO2 or H2S, must account for the relatively slow kinetics of mineral-gas-water interactions. We have therefore compiled parameters conforming to a general Arrhenius-type rate equation, for over 70 minerals, including phases from all the major classes of silicates, most carbonates, and many other non-silicates. The compiled dissolution rate constants range from -0.21 log moles...
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Results of physical and chemical analyses of sediment and water collected near a closed municipal landfill at Norman, Oklahoma are presented in this report. Sediment analyses are from 40 samples obtained by freeze-shoe coring at 5 sites, and 14 shallow (depth <1.3 m) sediment samples. The sediment was analyzed to determine grain size, the abundance of extractable iron species and the abundances and isotopic compositions of forms of sulfur. Water samples included pore water from the freeze-shoe core, ground water, and surface water. Pore water from 23 intervals of the core was collected and analyzed for major and trace dissolved species. Thirteen ground-water samples obtained from wells within a few meters of the...
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Exploration for and production of petroleum have caused major detrimental impacts to soils, surface and ground waters, and the local ecosystems in the United States. These impacts arise primarily from the improper disposal of large volumes of saline water produced with oil and gas, from accidental hydrocarbon and produced water releases, and from abandoned oil wells that were not correctly sealed. It is important to understand the long-term and short-term effects of produced water and hydrocarbon releases from these sites in order to develop risk-based remediation plans. Remediation is particularly needed in aging and depleted fields where land use is changing from petroleum production to residential, agricultural...
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Overview -- We have interpreted the geomorphology of the submerged landforms to show thick Holocene sediment that accumulated from three different sources during on-going sea level rise that began 10,000 - 12,000 years ago at the end of Pleistocene. We used a variety of subsurface data from the literature and unpublished information to document thicknesses, materials, dates and duration of processes. Although the details of the true extent and thicknesses are unknown, the deposits of different sources have affinity for particular geographic and submerged geomorphic regions of the Chesapeake Bay and its tidal tributaries. During the last Pleistocene glacial event (Wisconsian), the area now occupied by the Chesapeake...
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