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Evaluation of solid bitumen created from marine oil shale bituminite under hydrous and anhydrous pyrolysis conditions

Dates

Publication Date
Start Date
2021
End Date
2024

Citation

Hackley, P.C., Valentine, B.J., McAleer, R., Hatcherian, J.J., Nedzweckas, J.L., McDevitt, B., and Khan, I, 2024, Evaluation of solid bitumen created from marine oil shale bituminite under hydrous and anhydrous pyrolysis conditions: U.S. Geological Survey data release, https://doi.org/10.5066/P13E78PJ.

Summary

This study tests the influence of environmental conditions on conversion of the maceral bituminite to a solid petroleum residuum (solid bitumen) during pyrolysis. The presence of water in sedimentary basins controls multiple processes during petroleum generation, migration, and storage. Four organic-rich (26–36 wt.% total organic carbon) oil shale samples were collected from thin-bedded (several cm thick), discontinuous outcrop exposures in the Neoproterozoic–Lower Cambrian restricted marine Salt Range Formation in the upper Indus Basin, Pakistan. Samples were from the Khewra Gorge (K-2) and Sohan Nala localities [SN-R(c), SN-5(b), SN-1]; a sample of Joadja torbanite coal from Australia containing terrigenous vitrinite was also included [...]

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Table 1 Geochemical screening data for untreated samples.csv 319 Bytes text/csv
Table 2 Results from extraction, fractionation and gas chromatography analysis of untreated oil shales.csv 441 Bytes text/csv
Table 3 Geochemical screening data for hydrous pyrolysis residues.csv 1.74 KB text/csv
Table 4 Geochemical screening data for anhydrous and brine pyrolysis residues.csv 1.86 KB text/csv
Table 5 Results from gas chromatography analysis of oils generated from hydrous pyrolysis experiments.csv 3.49 KB text/csv
Table 6 Reflectance values for oil shales, Joadja coal, and hydrous pyrolysis residues.csv 1.96 KB text/csv
Table 7 Reflectance values for thucholite in sample SN-5(b) and hydrous pyrolysis residues.csv 435 Bytes text/csv

Purpose

The purpose of this study is to describe the response of sedimentary organic matter to heat treatments in different environmental conditions. This work was performed to better understand: i) how water behaves as a H donor during petroleum generation, ii) how brine can influence organic reactions during pyrolysis, and iii) how the presence or absence of water or brine can influence solid bitumen properties during thermal evolution.

Rights

This work is marked with Creative Commons Zero v1.0 Universal (https://creativecommons.org/publicdomain/zero/1.0/).

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Communities

  • Geology, Energy & Minerals (GEM) Science Center
  • USGS Data Release Products

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Additional Information

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Type Scheme Key
DOI https://www.sciencebase.gov/vocab/category/item/identifier doi:10.5066/P13E78PJ

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