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Germanium (Ge) is an increasingly important element used in critical technologies for communication, defense, and computing. However, Ge is scarce, and there is no United States (U.S.) primary production. Additionally, the environmental behavior of Ge is poorly understood. Germanium does not generally form its own minerals, but is instead recovered as a byproduct of zinc mining or of coal fly ash. It has been deemed critical by the U.S. and globally, and investigations of its geologic concentration, environmental fate and transport, and potential for recovery are crucial for maintaining a sustainable supply. A relevant study site to explore questions of environmental behavior and the potential to recover...
These data represent the air-free pH and specific conductance per pore volume of effluent generated by the phosphate removal column experiment. Solid samples used for the columns are of modern and legacy iron and steel slag from the Chicago-Gary area of Illinois and Indiana, USA.
These data include geochemical analyses of rock, mine waste, and water samples collected from the Balkhab copper deposit, Sar-e Pol Province, Afghanistan in 2020.
Categories: Data;
Tags: Afghanistan,
Mineral Resources,
USGS Science Data Catalog (SDC),
environmental chemistry,
geochemistry
The Ironwood Iron-Formation, part of the Gogebic Iron Range in Wisconsin, is a Paleoproterozoic Superior-type banded iron formation (BIF) with substantial iron resource potential. The development of a Mesoproterozoic contact metamorphic aureole related to the emplacement of the Mellen Intrusive Complex resulted in the production of a variety of silicate minerals in the western portion of the Ironwood Iron-Formation, including amphibole, pyroxene, and olivine. The presence of amphibole minerals, some of which occur in a fibrous habit, has complicated development of this resource due to potential human health impacts. This data release provides information related to amphibole and other minerals in order that commercial,...
These data represent the major, minor, and trace element compositions of effluent water samples generated by column experiments of modern and legacy iron and steel slag from the Chicago-Gary area of Illinois and Indiana. Details of the column experiments may be reviewed in the journal article listed in the cross-reference section of this data release titled, "Geochemical Characterization of Iron and Steel Slag and Its Potential to Remove Phosphate and Neutralize Acid".
Germanium (Ge) is an element deemed critical globally, and used in electronics, communication, and defense applications. The supply of Ge is limited and as demand for it increases, its criticality increases. Germanium is exclusively recovered as a byproduct of either coal mining or zinc (Zn) mining, and the main mineral hosting Ge in Zn deposits is sphalerite (ZnS). However, the mechanisms of Ge enrichment in sphalerite during mineral deposit formation are poorly understood. Therefore, investigations on the mechanisms controlling geologic enrichment of Ge in ores is crucial for maintaining a sustainable supply. For this study, we used a combination of techniques including optical and electron microscopy, synchrotron-based...
Stable hydrogen (H), oxygen (O), and sulfur (S) isotope data were collected from the Elizabeth copper mine Superfund site, South Strafford, Vermont. Sample media include surface water (H and O), groundwater (H and O), dissolved sulfate (O and S), and sulfide minerals in bulk mill tailings samples. Where available, supporting data for water samples include discharge, pH, specific conductance, and dissolved sulfate concentration. The water samples span a time period from August 1998 to October 2009.
Categories: Data;
Tags: Orange County,
USGS Science Data Catalog (SDC),
hydrogen isotope analysis,
mine drainage,
oxygen isotope analysis,
Electron microprobe analyses of sphalerite (ZnS) and hemimorphite (Zn4Si2O7(OH)2·H2O) from sampled historical waste piles were conducted with a specific focus on germanium (Ge). In mine wastes at the Tar Creek Superfund Site, Oklahoma, USA, Ge is associated with ZnS (sphalerite) as expected, but weathering in the waste piles has led to a significant amount of Ge being incorporated into a zinc-silicate, hemimorphite. Data and methods reported are part of a research study published here: White, S.J.O., Piatak, N.M., McAleer, R.J., Hayes. S.M., Seal, R.R. II, Schaider, L.A., Shine, J.P. Germanium redistribution during weathering of Zn mine wastes: implications for environmental mobility and recovery of a critical...
These data represent the acid neutralization potential and grain size analysis of 13 samples, 2 duplicate samples, of modern and legacy iron and steel slag from the Chicago-Gary area of Illinois and Indiana, USA.
Oxidation state and bonding environment of Ge and Cu in ZnS and Zn mineral concentrates from a variety of sources [Central Tennessee mining district (TN), Metaline mining district, (WA), and Red Dog mine (AK)] were determined by linear combination fits from x-ray absorption spectroscopy (XAS) analysis. Sphalerites from the East Tennessee mining district contained Ge in concentrations that were too low to generate a X-ray absorption spectra with an edge step. When applicable, Ge content in quartz was determined using XAS edge steps. Data and methods reported are part of a research study published in the 'Related External Resources' section below.
Mineral abundances within bulk and size-fractionated mine waste from sampled historical waste piles from the Tar Creek Superfund Site, Oklahoma, U.S.A., were determined by Mineral Liberation Analysis (MLA) and X-Ray Diffraction (XRD). Data and methods reported are part of a research study published here: White, S.J.O., Piatak, N.M., McAleer, R.J., Hayes. S.M., Seal, R.R. II, Schaider, L.A., Shine, J.P. Germanium redistribution during weathering of Zn mine wastes: implications for environmental mobility and recovery of a critical minerals, Applied Geochemistry, p. 105341, https://doi.org/10.1016/j.apgeochem.2022.105341
Categories: Data;
Types: Map Service,
OGC WFS Layer,
OGC WMS Layer,
OGC WMS Service;
Tags: Germanium,
Hemimorphite,
Mine Wastes,
Mineral Resources,
Oklahoma,
These data represent the major, minor, and trace element compositions of laboratory generated leachates of modern and legacy iron and steel slag from the Chicago-Gary area of Illinois and Indiana, USA using USEPA method 1312 Synthetic Precipitation Leaching Procedure.
Elemental concentrations for bulk and size-fractionated mine waste from sampled historical waste piles from the Tar Creek Superfund Site, Oklahoma, U.S. were determined after dissolution via acid digests or a sodium peroxide fusion. Elemental concentrations were determined for the leachate from a simulated rainwater leach of mine wastes. Data and methods reported are part of a research study published here: White, S.J.O., Piatak, N.M., McAleer, R.J., Hayes. S.M., Seal, R.R. II, Schaider, L.A., Shine, J.P. Germanium redistribution during weathering of Zn mine wastes: implications for environmental mobility and recovery of a critical mineral
This dataset comprises photomicrographs from drill core and outcrop samples from the Ironwood Iron-Formation.
These data comprise chemical analyses in weight percent of oxides, as well as chlorine and fluorine, conducted using a JEOL JXA-8900 electron microprobe analyzer (EPMA) on amphiboles, pyroxenes, and carbonates in the Ironwood Iron-Formation.
Categories: Data;
Tags: Ashland County,
Iron County,
Iron formation,
Wisconsin,
metamorphism (geological),
These data include geochemical analyses of rock, soil, sediment, and water samples collected from the Nuqra Khana iron deposit, Panjshir Province, Afghanistan in 2020.
Categories: Data;
Tags: Afghanistan,
Mineral Resources,
USGS Science Data Catalog (SDC),
environmental chemistry,
geochemistry
These worksheets contain data from geochemical analyses of solid mill tailings and other ore processing materials from worldwide localities, and leachates from those samples.
These data include geochemical analyses of rock, mine waste, soil, sediment, and water samples collected from the Balkhab copper deposit, Sar-e Pol Province, Afghanistan in 2019.
Categories: Data;
Tags: Afghanistan,
Geochemistry,
Mineral Resources,
USGS Science Data Catalog (SDC),
environmental chemistry,
This dataset comprises various energy-dispersive spectroscopy (EDS) analyses from drill core and outcrop samples in the Ironwood Iron-Formation, Gogebic Iron Range, Wisconsin, USA.
This worksheet displays the results of mineral abundance estimates based on Rietveld refinement of X-ray diffraction (XRD) analyses of mill tailings and other ore processing materials from worldwide localities. Data are also provided to show variation in mineral abundance estimates for subsplits in individual samples. Samples were analyzed using a PANalytical X'Pert Pro diffractometer using Cu radiation and the results interpreted using Highscore Plus v.4.7.
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