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Widespread nitrate contamination of groundwater in agricultural areas poses a major challenge to sustainable water resources. Efficient analysis of nitrate fluxes across large regions also remains difficult. This study introduces a method of characterizing nitrate transport processes continuously across regional unsaturated zones and groundwater based on surrogate, machine-learning metamodels of an N flux process-based model. The metamodels used boosted regression trees (BRTs) to relate mappable variables to parameters and outputs of a “vertical flux method” (VFM) applied in the Fox-Wolf-Peshtigo (FWP) area in Wisconsin. In this context, the metamodels are upscaling the VFM results throughout the region, and the...
High radium (Ra) concentrations in potable portions of the Cambrian-Ordovician (C-O) aquifer system were investigated using water-quality data and environmental tracers ( 3H, 3Hetrit, SF6 , 14C and 4Herad) of groundwater age from 80 public-supply wells (PSWs). Groundwater ages were estimated by calibration of tracers to lumped parameter models and ranged from modern (1 Myr) in the most downgradient, confined portions of the potable system. More than 80 and 40 percent of mean groundwater ages were older than 1000 and 50,000 yr, respectively. Anoxic, Fe-reducing conditions and increased mineralization develop with time in the aquifer system and mobilize Ra into solution resulting in the frequent occurrence of combined...
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