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Concentrations of inorganic constituents, dissolved organic carbon (DOC), tritium, per- and polyfluoroalkyl substances (PFAS), volatile organic compounds (VOCs), and pharmaceuticals were measured in groundwater samples collected from 254 wells in 2019 and 2020. Concentrations of inorganic constituents, DOC, VOCs, and pharmaceuticals were measured at the U.S. Geological Survey (USGS) National Water Quality Laboratory in Lakewood, Colorado. Concentrations of tritium were measured at the USGS Tritium Laboratory in Menlo Park, California. Concentrations of PFAS were measured at SGS Laboratory in Orlando, Florida. In addition, several geospatial parameters were determined, including: percentages of selected land uses...
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In a study conducted by the U.S. Geological Survey (USGS) and the New Hampshire Department of Environmental Services, detectable concentrations of per- and polyfluoroalkyl substances (PFAS) were found in the soil at every site despite targeting locations with no known PFAS sources (Santangelo and others, 2022). The widespread distribution of PFAS concentrations in New Hampshire has since sparked critical interest into understanding whether recharge to groundwater contains significant concentrations of PFAS after infiltration through soils. To address this concern, the USGS implemented a pilot study designed to evaluate whether PFAS infiltrate through shallow soil into shallow groundwater. Five sites were selected...
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State and local county health departments have detected per- and polyfluoroalkyl substances (PFAS) in groundwater downgradient of airports and military and firefighting training areas in Long Island, New York. However, the occurrence and spatial distribution of PFAS throughout the surficial aquifer is not well established. Shallow groundwater samples were collected in 2018 from two observation well networks; the Sentinel network and Wastewater Treatment Plant groundwater (WTPGW) network. The Sentinel network is an island-wide group of wells screened within the shallow upper glacial (surficial, <100 feet deep) aquifer, which were sampled to assess the occurrence of PFAS in different land-use settings. The WTPGW network...
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This dataset contains the concentration and quality assurance results for 34 per- and polyfluoroalkyl substances (PFAS). 409 residential and commercial tapwater samples were collected once between May 2021 and May 2022, in the contiguous U.S., Alaska, Hawaii, Puerto Rico, and U.S. Virgin Islands. Of these samples 252 were from publicly supplied tapwater locations, and 155 were sourced from private wells, springs or catchment vessels. Additionally, three surface-water samples were collected in New Hampshire (as denoted with a site code suffix of '_SW' in Table 2a). An additional 85 samples were collected at 3 locations (privately sourced tapwater samples in New Jersey (30) and South Carolina (20), and a publicly...
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Per- and polyfluoroalkyl substances (PFAS) and related chemical and physical data are presented from 100 shallow soil sampling locations within the State of New Hampshire. Sites were randomly determined through an equal-area grid approach (Scott, 1990) targeting undisturbed areas, which included lands classified by the 2016 National Land Cover Database (Dewitz, 2019) as forested, shrubland, scrubland, grassland, herbaceous, wetlands, or barren land. Sampling sites were located at the closest point to the random location identified, where access and permission were available. To limit the potential for sampling results to be influenced by local releases of PFAS, a 500-meter buffer around parcels associated with known...
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Water-quality samples were collected at 49 surface water sites covering a range of land uses across the state of Iowa starting the summer of 2022 and continuing into the spring of 2023 by staff from the U.S. Geological Survey Central Midwest Water Science Center. Samples were submitted to the National Water Quality Laboratory in Denver, Colorado, and were analyzed for 32 per- and polyfluoroalkyl substances. Additional samples for N-(1,3-Dimethylbutyl)-N’-phenyl-p-phenylenediamine (6PPD) and 6PPD-Quinone were sent from a subset of the sites to the Organic Geochemistry Research Laboratory in Lawrence, Kansas.
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Data were collected at 19 groundwater monitoring wells and 3 surface water locations across McHenry County, Illinois, in 2020 by staff from the U.S. Geological Survey (USGS) Central Midwest Water Science Center. Quality control samples (2 blanks and 1 replicate) were also collected to assess data reliability and precision. Samples were submitted to the USGS National Water Quality Laboratory in Denver, Colorado, and analyzed for per- and polyfluoroalkyl (PFAS) substances in late 2022 and results provided in April of 2023. PFAS were detected in 16 of the 19 groundwater monitoring wells and in all 3 surface water sites sampled.
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Water resources around the world are contaminated with per- and polyfluoroalkyl substances (PFAS) due to releases from point sources on military installations, fire training centers, and chemical manufacturing sites. Non-point sources have also been identified including wastewater effluent, landfills, and biosolids application. PFAS are a major concern to myriad stakeholders as some are known to bioaccumulate, they have eco-toxicity effects, and they are highly recalcitrant. PFAS are often called “forever chemicals” due to their environmental persistence but many precursor PFAS are transformed in the environment by microbes. Recent work has shown that PFAS can be biologically degraded in laboratory studies, but...
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This data release presents results of chemical analyses of groundwater sampled during summer and autumn of 2019 and spring of 2020 from 23 wells in the Great Miami buried-valley aquifer (GM-BVA) of southwestern Ohio. Groundwater and quality-control samples were analyzed to determine concentrations of selected per- and polyfluoroalkyl substances (PFAS). Groundwater and related quality-control samples were collected from 22 of 23 wells and analyzed for 24 different PFAS by two different laboratories that used slightly different proprietary isotope-dilution based adaptations of U.S. Environmental Protection Agency (USEPA) method 537.1, referred to as method 1 and method 2. Results from PFAS analysis of groundwater...
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This dataset contains a compilation of concentrations of chlorinated volatile organic compounds (VOCs) and per- and polyfluoroalkyl substances (PFAS) in groundwater and surface water sampled at the former Naval Air Warfare Center, West Trenton, New Jersey. Measured VOCs include trichloroethene (TCE), cis- 1,2-dichloroethene (cisDCE), and vinyl chloride (VC). Semi-volatile organic compound 1,4-dioxane is also included. Measured PFAS include perfluorooctane sulfonate (PFOS), perfluorooctanoic acid (PFOA), perfluorononanoic acid (PFNA), perfluorobutane sulfonate (PFBS), perfluorohexane sulfonate (PFHxS), perfluorohexanoic acid (PFHxA), perfluoroheptanoic acid (PFHpA), perfluorodecanoic acid (PFDA), perfluoroundecanoic...
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This United States Geological Survey (USGS) data release contains Darcy flux and mass flux of per- and polyfluoroalkyl substances (PFAS) measured using passive flux meters (PFMs) in monitoring wells associated with the Cannon Air Force Base (CAFB) in Clovis, New Mexico. The measurements were conducted by the USGS in cooperation with CAFB, the Air Force Civil Engineer Center, AECOM (an engineering consulting firm), and the University of Florida.
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Lake-bottom sediment and associated quality-control samples were collected in August 2020 from one coring location (U.S. Geological Survey station 413756070321301, ASHUMET POND, MASHPEE MI-ASHPD-0011) in Ashumet Pond downgradient from a former fire-training area on Cape Cod, Massachusetts. The core was collected to determine if per- and polyfluoroalkyl substances (PFAS) were present in the bottom sediments of a lake known to have elevated concentrations of PFAS in surface water and groundwater (Tokranov and others, 2021), and whether the sediments could act as a continuous source of PFAS to the lake. Processing the sediment core entailed collection of discrete samples at intervals ranging from 1-5 centimeters (cm)...
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This data release presents chemical and biological results from an investigation of the uptake of per- and polyfluoroalkyl substances (PFAS) from groundwater contaminated by fire training activities on Cape Cod, Massachusetts conducted from July to August 2019. An exposure experiment was conducted at an a PFAS contaminated site (FTA-1) near the fire training area (FTA). To assess the tissue-specific uptake characteristics of the mixture of PFAS present in the groundwater from the FTA-1 site, a 21-day mobile laboratory exposure experiment was conducted. Details for the groundwater sampling sites and well construction are presented (Table 1). The PFAS mixture concentrations and composition in groundwater and in fish...
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Anaerobic microcosm experiments were conducted in April-May 2018 with PFAS-contaminated soil from a U.S. Army installation (Fort Drum, New York) and simulated groundwater. All microcosms, except for a live sediment control, were amended with perfluorooctanesulfonate (PFOS), perfluorooctanoate (PFOA), and 6:2 fluorotelomer sulfonate (6:2 FtS). Replicate treatments were prepared with and without bioaugmentation with the WBC-2 dehalogenating culture and with and without addition of chlorinated volatile organic compounds (1,1,2,2-tetrachloroethane and trichloroethylene). Two additional treatments were prepared containing granular activated carbon. All microcosms were prepared in duplicate and sacrificed for sampling....
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The U.S. Geological Survey collected groundwater samples from 71 wells used for domestic and small system drinking water supplies in Stanislaus and Merced counties of California during 2020-2021. The wells were sampled for the Modesto-Turlock-Merced Domestic-Supply Aquifer Study Unit of the State Water Resources Control Board Groundwater Ambient Monitoring and Assessment (GAMA) Program Priority Basin Project’s assessment of the quality of groundwater resources used for domestic and small system drinking water supplies. The study unit was defined by the extent of the Modesto, Turlock, and Merced subbasins of the San Joaquin Valley groundwater basin. The study unit was divided into 62 grid cells and one or more domestic...
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A three-dimensional groundwater flow model using MODFLOW 6 (version 6.2.2) was developed and calibrated for unconsolidated Coastal Plain aquifers underlying the Joint Base McGuire-Dix-Lakehurst (JBMDL) and vicinity, New Jersey, to evaluate groundwater flow pathways of per- and polyfluoroalkyl substances (PFAS) contamination associated with use of aqueous film forming foam (AFFF). The model was developed and calibrated by the U.S. Geological Survey (USGS) in cooperation with the U.S. Air Force Civil Engineer Center (AFCEC) based on the previously developed hydrogeologic framework (https://doi.org/10.3133/ofr20191134). Steady-state flow in the unconsolidated aquifers was simulated using the MODFLOW 6 which accounts...
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This data set is from a study examining the flow of per- and polyfluoroalkyl substances (PFAS) through food webs. The data are PFAS concentrations in gastrointestinal contents of tree swallows.
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This dataset consists of summary data for potential landscape sources of per- and poly-fluoroalkyl substances (PFAS). These summary items include facilities from the Environmental Protection Agency (EPA) PFAS Analytics Tools, which were pulled from its Enforcement and Compliance History Online (ECHO), areas affected by fires (burned and urban burned areas) from Monitoring Trends in Burn Severity (MTBS), and landcover data from National Land Cover Dataset (NLCD) and Coastal Change Analysis Portal (C-CAP) around sites sampled as part of a National PFAS Tapwater Reconnaissance. These data are presented as a comma separated file, which includes summaries for all variables listed within a 5-kilometer buffer around each...
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Data for per- and polyfluoroalkyl substances (PFAS) and related chemical and physical characteristics are presented from 30 soil sampling locations within the State of New Hampshire. A total of 15 sites were chosen based on the results of sampling efforts published in Santangelo and others(2022). Sites with relatively high concentrations of PFAS observed during the first study were selected for resampling to better understand the range of concentrations of PFAS in the area. At each of the 15 sites, soil samples were collected as near to the original site as possible (site A), and a second set of soil samples were collected at a secondary location (site B) 50 to 600 feet away from the original location for a total...
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These data were collected to understand the occurrence of per- and polyfluoroalkyl substances (PFAS) in drinking water samples at public water systems identified to have perfluorooctanoic acid (PFOA) or perfluorooctane sulfonic acid (PFOS) above laboratory reporting levels in previously collected raw-water samples (Mcadoo and others, 2022), and provide a review of the analytical results.These data are stored in the USGS National Water Information System (NWIS) but are not available to the public from that platform because West Virginia State Law §22-26-4, and USGS policy concerning the release of sensitive water related information, prohibits the release of public water system infrastructure location information....