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Germanium (Ge) is an increasingly important element used in critical technologies for communication, defense, and computing. However, Ge is scarce, and there is no United States (U.S.) primary production. Additionally, the environmental behavior of Ge is poorly understood. Germanium does not generally form its own minerals, but is instead recovered as a byproduct of zinc mining or of coal fly ash. It has been deemed critical by the U.S. and globally, and investigations of its geologic concentration, environmental fate and transport, and potential for recovery are crucial for maintaining a sustainable supply. A relevant study site to explore questions of environmental behavior and the potential to recover...
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This data release includes 40Ar/39Ar data from the U.S. Geological Survey for samples from Old Mine Park Area, Trumbull, Connecticut. Mineral samples were collected by Robert Wintsch and Harold Moritz. Potassium-bearing mineral grains were separated from the bulk sample and analyzed by argon geochronology at the U.S. Geological Survey Bascom ARgon Dating (BARD) Laboratory in Reston, Virginia. The data provide age constraints on units in the relevant geologic mapping area.
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These data are U-Pb sensitive high-resolution ion microprobe (SHRIMP) geochronology data from quartz porphyry dikes for the study of the Butte mining district, U.S.A. Results of the study are described and interpreted in Lund and others (2018).
The Ironwood Iron-Formation, part of the Gogebic Iron Range in Wisconsin, is a Paleoproterozoic Superior-type banded iron formation (BIF) with substantial iron resource potential. The development of a Mesoproterozoic contact metamorphic aureole related to the emplacement of the Mellen Intrusive Complex resulted in the production of a variety of silicate minerals in the western portion of the Ironwood Iron-Formation, including amphibole, pyroxene, and olivine. The presence of amphibole minerals, some of which occur in a fibrous habit, has complicated development of this resource due to potential human health impacts. This data release provides information related to amphibole and other minerals in order that commercial,...
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The refractory nature of zircon to temperature and pressure allows even a single zircon grain to preserve a rich history of magmatic, metamorphic, and hydrothermal processes. Isotopic dating of micro-domains exposed in cross-sections of zircon grains allows us to interrogate this history. Unfortunately, our ability to select the zircon grains in a heavy mineral concentrate that records the most geochronologic information is limited by our inability to predict internal zonation from observations of whole zircon grains. Here we document the use of a petrographic microscope to observe and image the photoluminescence (PL) response of whole zircon grains excited under ultraviolet (UV) light, and the utility of this PL...
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This data release includes 40Ar/39Ar collected at the U.S. Geological Survey for samples from the Janub Metamorphic Complex in Southern Jordan. Rock samples were collected by Hind Ghanem of the University of Jordan. Muscovite-rich microcores were drilled from a polished thick section of a deformed granitoid and analyzed by argon geochronology at the U.S. Geological Survey Bascom ARgon Dating (BARD) Laboratory in Reston, Virginia. The 40Ar/39Ar data constrain the timing of formation of the foliation defined by muscovite.
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This data release includes 40Ar/39Ar data from the U.S. Geological Survey for samples from the Gidami gold deposit in the Eastern Desert of Egypt. Rock samples were collected by Basem Zoheir--Benha University/University of Kiel. Potassium-bearing mineral grains were separated from the bulk sample and analyzed by argon geochronology at the U.S. Geological Survey Bascom ARgon Dating (BARD) Laboratory in Reston, Virginia. The data constrain the timing of gold mineralization in the Gidami gold deposit.
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Iron oxide-apatite (IOA) deposits of the Adirondack Mountains of New York locally contain elevated REE concentrations (e.g. Taylor and others, 2019). Critical to evaluating resource potential is understanding the genesis of the IOA deposits that host the REE-rich minerals. As part of this effort, the U.S. Geological Survey (USGS) is conducting bedrock geologic mapping, geochronology, geochemistry, and geophysics in the region. Published and ongoing research demonstrates the spatial association of IOA deposits with the Lyon Mountain Granite Gneiss (LMG), so understanding the relationship of the LMG to the IOA deposits is important for resource evaluation—however the age and origin of the LMG remain contentious. As...
Geological models for petroleum generation suggest thermal conversion of oil-prone sedimentary organic matter in the presence of water promotes increased liquid saturate yield, whereas absence of water causes formation of an aromatic, cross-linked solid bitumen residue. To test the influence of exchangeable hydrogen from water, organic-rich (22 wt.% total organic carbon, TOC) mudrock samples from the Eocene lacustrine Green River Mahogany zone oil shale were pyrolyzed under hydrous and anhydrous conditions at temperatures between 300 and 370°C for 72 hrs. Petrographic approaches including optical microscopy, reflectance, Raman spectroscopy, and scanning electron and transmission electron microscopy, supplemented...
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Germanium (Ge) is an element deemed critical globally, and used in electronics, communication, and defense applications. The supply of Ge is limited and as demand for it increases, its criticality increases. Germanium is exclusively recovered as a byproduct of either coal mining or zinc (Zn) mining, and the main mineral hosting Ge in Zn deposits is sphalerite (ZnS). However, the mechanisms of Ge enrichment in sphalerite during mineral deposit formation are poorly understood. Therefore, investigations on the mechanisms controlling geologic enrichment of Ge in ores is crucial for maintaining a sustainable supply. For this study, we used a combination of techniques including optical and electron microscopy, synchrotron-based...
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This data release contains photographs and photomicrographs from drill cores and cuttings of pre-Middle Jurassic basement rocks that are buried beneath Coastal Plain sedimentary deposits in Florida. These samples provide rare insights into deeply buried rocks that have no surface exposures and no known exposed correlates. These images were acquired to support the characterization, discrimination, and correlation of map units comprising Florida’s basement infrastructure (Deasy and others, 2024a). These are the original images. Annotated images with additional comments are available in the companion Data Report (Deasy and others, 2024b). Semi-quantitative mineral modes of many basement rocks are presented in a companion...
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Electron microprobe analyses of sphalerite (ZnS) and hemimorphite (Zn4Si2O7(OH)2·H2O) from sampled historical waste piles were conducted with a specific focus on germanium (Ge). In mine wastes at the Tar Creek Superfund Site, Oklahoma, USA, Ge is associated with ZnS (sphalerite) as expected, but weathering in the waste piles has led to a significant amount of Ge being incorporated into a zinc-silicate, hemimorphite. Data and methods reported are part of a research study published here: White, S.J.O., Piatak, N.M., McAleer, R.J., Hayes. S.M., Seal, R.R. II, Schaider, L.A., Shine, J.P. Germanium redistribution during weathering of Zn mine wastes: implications for environmental mobility and recovery of a critical...
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This data release includes whole rock (WR) geochemical data for 94 samples. Whole rock geochemistry data were analyzed at Actlabs in Ancaster, Ontario, Canada. Rock samples were collected by Peter Valley, Greg Walsh, Arthur Merschat, and Ryan McAleer. The whole rock geochemistry data characterize the composition of mapped meta-igneous rocks in eastern Vermont and western New Hampshire, USA. The data release contains three files, including one metadata file and 2 comma-delimited (CSV) files. The CSV files include the following: BronsonHill_WR_data.csv and BronsonHill_WR_data_dictionary.csv.
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Oxidation state and bonding environment of Ge and Cu in ZnS and Zn mineral concentrates from a variety of sources [Central Tennessee mining district (TN), Metaline mining district, (WA), and Red Dog mine (AK)] were determined by linear combination fits from x-ray absorption spectroscopy (XAS) analysis. Sphalerites from the East Tennessee mining district contained Ge in concentrations that were too low to generate a X-ray absorption spectra with an edge step. When applicable, Ge content in quartz was determined using XAS edge steps. Data and methods reported are part of a research study published in the 'Related External Resources' section below.
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High-resolution scanning electron microscopy (SEM) visualization of sedimentary organic matter (SOM) is widely utilized in the geosciences for evaluation of microscale rock properties relevant to depositional environment, diagenesis, and the processes of fluid generation, transport, and storage. However, despite thousands of studies which have incorporated SEM approaches, the inability of SEM to differentiate SOM types has hampered the pace of scientific advancement. In this study, we show that SEM-cathodoluminescence (CL) properties can be used to identify and characterize SOM at low thermal maturity conditions. Eleven varied mudstone samples with a broad array of SOM types, ranging from the Paleoproterozoic to...
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This data release includes whole rock (WR) geochemical data, and uranium-lead isotopic data collected using a sensitive high resolution ion microprobe-reverse geometry (SHRIMP-RG) instrument; the SHRIMP-RG is a type of secondary ion mass spectrometer (SIMS). Whole rock geochemistry data were analyzed at Bureau Veritas Commodities Canada Ltd. Laboratories in Vancouver, British Columbia, Canada. SHRIMP-RG data were collected at the USGS-Stanford University SHRIMP-RG in Palo Alto, California, USA. Rock samples for all methods were collected by Phillip Geer, Sean Regan, and Greg Walsh. SHRIMP-RG sample preparation and analyses were conducted by Ryan McAleer. The whole rock geochemistry and uranium-lead (U-Pb) isotopic...
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This data release includes electron 40Ar/39Ar collected at the U.S. Geological Survey for samples from the Day Nui Con Voi metamorphic massif, Vietnam. Rock samples were collected by Meng-Wan Yeh, Michael J. Kunk and Robert P Wintsch in 2011. Mineral separates were prepared and aliquots of amphibole, muscovite, phlogopite, biotite, and potassium feldspar were analyzed by the 40Ar/39Ar method at the U.S. Geological Survey Bascom ARgon Dating (BARD) Laboratory in Reston, Virginia. The 40Ar/39Ar data constrain the timing of exhumation of rocks within the massif.
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Backscatter electron (BSE) and panchromatic cathodoluminescent (CL) imagery of minerals from samples dated by 40Ar/39Ar are for the study of the Butte mining district, U.S.A. Results of the study are described and interpreted in Lund and others (2018).These data are shared to meet open data requirements.
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Mineral abundances within bulk and size-fractionated mine waste from sampled historical waste piles from the Tar Creek Superfund Site, Oklahoma, U.S.A., were determined by Mineral Liberation Analysis (MLA) and X-Ray Diffraction (XRD). Data and methods reported are part of a research study published here: White, S.J.O., Piatak, N.M., McAleer, R.J., Hayes. S.M., Seal, R.R. II, Schaider, L.A., Shine, J.P. Germanium redistribution during weathering of Zn mine wastes: implications for environmental mobility and recovery of a critical minerals, Applied Geochemistry, p. 105341, https://doi.org/10.1016/j.apgeochem.2022.105341
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This data release includes whole rock geochemical data, and uranium-lead isotopic data collected by both Laser Ablation Inductively Coupled Plasma Mass Spectrometry (LA-ICP-MS) and Sensitive High Resolution Ion Microprobe-Reverse Geometry (SHRIMP-RG) methods. Whole rock geochemistry was collected by Activation Laboratories in Ancaster, Ontario. LA-ICP-MS data was collected at the PLASMA at the USGS in Denver, Colorado. SHRIMP-RG data was collected at the USGS-Stanford SHRIMP-RG in Palo Alto, California. Rock samples for all methods were collected by Mark Carter of the USGS. The whole rock geochemistry and uranium lead isotopic data constrain the age and origin of rocks in the newly defined Dinwiddie Terrane of eastern...


map background search result map search result map 1) U-Pb SHRIMP Age Data 4) BSE & CL Imagery Electron microprobe analyses of feldspars and petrographic, geochemical, and geochronologic data from the Hawkeye Granite Gneiss and Lyon Mountain Granite Gneiss in the Adirondacks of New York (ver. 2.0, May 2023) Photoluminescence Imaging of Whole Zircon Grains on a Petrographic Microscope—An Underused Aide for Geochronologic Studies TOC, Reflectance and Raman Data from Eocene Green River Mahogany zone 40Ar/39Ar data from the Old Mine Park area, Trumbull, Connecticut Electron microprobe analyses of sphalerite and hemimorphite from mine wastes from the Tar Creek Superfund Site, Tri-State Mining District, Oklahoma, U.S.A. Geochemical, mineralogical, and molecular scale speciation characterization of mine wastes from the Tar Creek Superfund Site, Tri-State Mining District, Oklahoma, U.S.A. 40Ar/39Ar data from the Gidami gold deposit, Egypt Mineral abundances within bulk and size-fractionated mine waste from the Tar Creek Superfund Site, Tri-State Mining District, Oklahoma, U.S.A. Molecular-scale speciation of germanium and copper within sphalerite from Central Tennessee mining district (TN), Red Dog mining district (AK), and Metaline mining district (WA) Whole Rock Geochemistry and Uranium Lead Isotopic Data from the Dinwiddie Terrane, Virginia, USA 40Ar/39Ar data from the Janub Metamorphic Complex, Southern Jordan Trace element composition and molecular-scale speciation characterization of sphalerite from Central and East Tennessee mining districts, Red Dog mining district (AK), and Metaline mining district (WA) Whole rock geochemistry and uranium-lead isotopic data from Mesoproterozoic rocks in the Eagle Lake quadrangle, Essex County, New York 40Ar/39Ar isotopic data from the Day Nui Con Voi metamorphic massif, Vietnam SEM-CL investigation of sedimentary organic matter samples Whole rock geochemistry data from the Ordovician Bronson Hill arc and Silurian and Devonian Connecticut Valley - Gaspé trough, Vermont and New Hampshire Photographs and photomicrographs of selected pre-Middle Jurassic basement rocks beneath the Atlantic and Gulf Coastal Plains in Florida Whole rock geochemistry and uranium-lead isotopic data from Mesoproterozoic rocks in the Eagle Lake quadrangle, Essex County, New York 40Ar/39Ar data from the Old Mine Park area, Trumbull, Connecticut 40Ar/39Ar data from the Gidami gold deposit, Egypt 1) U-Pb SHRIMP Age Data 4) BSE & CL Imagery Electron microprobe analyses of sphalerite and hemimorphite from mine wastes from the Tar Creek Superfund Site, Tri-State Mining District, Oklahoma, U.S.A. Mineral abundances within bulk and size-fractionated mine waste from the Tar Creek Superfund Site, Tri-State Mining District, Oklahoma, U.S.A. 40Ar/39Ar data from the Janub Metamorphic Complex, Southern Jordan Whole Rock Geochemistry and Uranium Lead Isotopic Data from the Dinwiddie Terrane, Virginia, USA Geochemical, mineralogical, and molecular scale speciation characterization of mine wastes from the Tar Creek Superfund Site, Tri-State Mining District, Oklahoma, U.S.A. Electron microprobe analyses of feldspars and petrographic, geochemical, and geochronologic data from the Hawkeye Granite Gneiss and Lyon Mountain Granite Gneiss in the Adirondacks of New York (ver. 2.0, May 2023) TOC, Reflectance and Raman Data from Eocene Green River Mahogany zone Photographs and photomicrographs of selected pre-Middle Jurassic basement rocks beneath the Atlantic and Gulf Coastal Plains in Florida 40Ar/39Ar isotopic data from the Day Nui Con Voi metamorphic massif, Vietnam Photoluminescence Imaging of Whole Zircon Grains on a Petrographic Microscope—An Underused Aide for Geochronologic Studies Molecular-scale speciation of germanium and copper within sphalerite from Central Tennessee mining district (TN), Red Dog mining district (AK), and Metaline mining district (WA) Trace element composition and molecular-scale speciation characterization of sphalerite from Central and East Tennessee mining districts, Red Dog mining district (AK), and Metaline mining district (WA) SEM-CL investigation of sedimentary organic matter samples